However for a more focused exposure in your own country e.g. UK

We can create a new Geo Zone as UK (United Kingdom) especially for the purposes of setting a new Tax like VAT which is unique to that zone and not to all World Zones.

  1. Go to Admin>Payment>Tax>Zones and create a New Zone as UK – United Kingdom

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Further Edit this listing to select 'country'

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2. Next you should create the TAX that you require, in this example VAT at 20%

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3. Create the Tax Rate Admin>Payment>Tax>Rates

And select the new zone = UK

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Now we can also go back to our Admin>Payments and select UK for a payment zones if required.